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When solar panels are out in the sun the materials within it release electrons which then produce electricity.
How it Works
http://wattsee.com/10-great-reasons-buy-solar-panels-home
http://app.discoveryeducation.com/player/view?assetGuid=54b95211-7fea-4432-bf8f-b18943b563
79&showBreadcrumbs=true
And when it does that you can get electricity
http://blog.cleanenergy.org/2013/04/03/there-is-no-such-thing-as-a-solar-ash-spill/solarpanels-2/