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After the ban on Opium, two German scientists created Oxycodone in 1916. It was marketed as a synthetic, non-addictive alternative to Opium.
In 1996, Perdue Pharma released OxyContin
Start of Oxycodone & Hydrocodone
Hydrocodone was invented in the 1920's by Knoll, a German pharmaceutical company. It was believed to make Codeine less toxic to the user.